OK, here is the contents of the log file with username info deleted. The desktop at the church is running Windows 7 Home Premium with Service Pack 1. We are using version 11.55 of PCPlus as you indicated:
<SessionLog>
<Begin>2016-01-05T07:25:17</Begin>
<LogEntry>
<EntryTime>2016-01-05T07:25:49</EntryTime>
<Log><numprocessed>0</numprocessed>
<numtoprocess>1</numtoprocess>
<recipients>
bryantmom4@gmail.com;</recipients>
<SmtpFailReason>ConnectFailed</SmtpFailReason>
<ChilkatLog>
<OpenSmtpConnection>
<DllDate>Aug 26 2015</DllDate>
<ChilkatVersion>9.5.0.52</ChilkatVersion>
<UnlockPrefix>POWERC.CBX0717</UnlockPrefix>
<Username> deleted </Username>
<Architecture>Little Endian; 32-bit</Architecture>
<Language>ActiveX</Language>
<VerboseLogging>0</VerboseLogging>
<ensureSmtpSession>
<ensureSmtpConnection>
<SmtpHost>smtp.att.yahoo.net</SmtpHost>
<SmtpPort>465</SmtpPort>
<SmtpUsername> deleted </SmtpUsername>
<SmtpSsl>1</SmtpSsl>
<StartTLS>0</StartTLS>
<smtpConnect>
<smtpHostname>smtp.att.yahoo.net</smtpHostname>
<smtpPort>465</smtpPort>
<connectionIsReady>
<info>Need new SMTP connection</info>
</connectionIsReady>
<smtpSocketConnect>
<socket2Connect>
<connect2>
<connectImplicitSsl>
<connectSocket>
<connect_ipv6_or_ipv4>
<resolveHostname6>
<getAddressInfo>
<error>Failed to get host address info. (3)</error>
<SocketError>WSAHOST_NOT_FOUND No such host is known.</SocketError>
<hostOrIpAddr>smtp.att.yahoo.net</hostOrIpAddr>
<port>465</port>
<info>Versions of Windows earlier than Windows XP are limited to handling IPv4 only</info>
<info>On Windows Server 2003 and Windows XP, IPv6 addresses are returned only if IPv6 is installed on the local computer.</info>
</getAddressInfo>
</resolveHostname6>
<error>Domain to IP address resolution failed.</error>
</connect_ipv6_or_ipv4>
</connectSocket>
</connectImplicitSsl>
<ConnectFailReason>DNS lookup failed</ConnectFailReason>
</connect2>
</socket2Connect>
<error>Failed to connect to SMTP server..</error>
</smtpSocketConnect>
</smtpConnect>
</ensureSmtpConnection>
</ensureSmtpSession>
<error>Failed to connect to SMTP server</error>
<error>Failed.</error>
</OpenSmtpConnection>
</ChilkatLog>
</Log>
</LogEntry>
<LogEntry>
<EntryTime>2016-01-05T07:25:50</EntryTime>
<Log><numprocessed>0</numprocessed>
<numtoprocess>1</numtoprocess>
<recipients>
bryantmom4@gmail.com;</recipients>
<ChilkatLog>
<CloseSmtpConnection>
<DllDate>Aug 26 2015</DllDate>
<ChilkatVersion>9.5.0.52</ChilkatVersion>
<UnlockPrefix>POWERC.CBX0717</UnlockPrefix>
<Username> deleted </Username>
<Architecture>Little Endian; 32-bit</Architecture>
<Language>ActiveX</Language>
<VerboseLogging>0</VerboseLogging>
</CloseSmtpConnection>
</ChilkatLog>
</Log>
</LogEntry>
<End>2016-01-05T07:26:35</End>
</SessionLog>